Trifunctional Metal Ion-Catalyzed Solvolysis: Cu(II)-Promoted Methanolysis of N,N-bis(2-picolyl) Benzamides Involves Unusual Lewis Acid Activation of Substrate, Delivery of Coordinated Nucleophile, Powerful Assistance of the Leaving Group Departure-Reference-Cited by-同舟云学术

Trifunctional Metal Ion-Catalyzed Solvolysis: Cu(II)-Promoted Methanolysis of N,N-bis(2-picolyl) Benzamides Involves Unusual Lewis Acid Activation of Substrate, Delivery of Coordinated Nucleophile, Powerful Assistance of the Leaving Group Departure

Published:2012-09-12 Issue:19 Volume:51 Page:10325-10333
ISSN:0020-1669
Container-title:Inorganic Chemistry
language:en
Short-container-title:Inorg. Chem.

Author:

Raycroft Mark A. R.¹,Maxwell Christopher I.¹,Oldham Robyn A. A.¹,Andrea Areen Saffouri¹,Neverov Alexei A.¹,Brown R. Stan¹

Affiliation:

1. Department of Chemistry, Queen’s University, Kingston, Ontario, Canada K7L 3N6

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/ic301454y

Reference86 articles.

1. Acyl and phosphoryl transfer to methanol promoted by metal ions

2. 2004 Bader Award LectureMetal-ion-catalyzed acyl and phosphoryl transfer reactions to alcohols: La3+-promoted alcoholysis of activated amides, carboxylate esters, and neutral organophosphorus esters

3. Dinuclear Zn(II) catalysts as biomimics of RNA and DNA phosphoryl transfer enzymes: changing the medium from water to alcohol provides enzyme-like rate enhancements

4. Brown, R. S.InProgress in Inorganic Chemistry;Karlin, K., Ed.John Wiley and Sons:New York, 2011, Vol.57, p55, and references therein.

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