Transition from concerted to stepwise processes as a function of leaving group ability: density functional theory and experimental study of lyoxide-promoted cleavages of phosphorothioate and phosphate triesters in water and methanol-Reference-Cited by-同舟云学术

Transition from concerted to stepwise processes as a function of leaving group ability: density functional theory and experimental study of lyoxide-promoted cleavages of phosphorothioate and phosphate triesters in water and methanol

Published:2011-10-21 Issue:5 Volume:25 Page:437-449
ISSN:0894-3230
Container-title:Journal of Physical Organic Chemistry
language:en
Short-container-title:J. Phys. Org. Chem.

Author:

Maxwell Christopher I.¹,Liu C. Tony¹,Neverov Alexei A.¹,Mosey Nicholas J.¹,Brown Robert Stan¹

Affiliation:

1. Department of Chemistry; Queen's University; Kingston Ontario Canada K7L 3N6

Funder

NSERC Canada

US Defense Threat Reduction Agency-Joint Science and Technology Office, Basic and Supporting Sciences Division

Publisher

Wiley

Subject

Organic Chemistry,Physical and Theoretical Chemistry

Link

http://onlinelibrary.wiley.com/wol1/doi/10.1002/poc.1938/fullpdf

Reference68 articles.

1. Why Nature Chose Phosphates

2. Metal Activation of Enzymes in Nucleic Acid Biochemistry

3. Mode of Action of Bi- and Trinuclear Zinc Hydrolases and Their Synthetic Analogues

4. Binuclear Metallohydrolases

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