Competing pathways for photoremovable protecting groups: the effects of solvent, oxygen and encapsulation-Reference-Cited by-同舟云学术

Competing pathways for photoremovable protecting groups: the effects of solvent, oxygen and encapsulation

Published:2020 Issue:10 Volume:19 Page:1364-1372
ISSN:1474-905X
Container-title:Photochemical & Photobiological Sciences
language:en
Short-container-title:Photochem. Photobiol. Sci.

Author:

Field Thomas¹²³⁴,Peterson Julie¹²³⁴^ORCID,Ma Chicheng¹²³⁴^ORCID,Jagadesan Pradeepkumar¹⁵⁶⁴^ORCID,Da Silva José P.⁷⁸⁹¹⁰^ORCID,Rubina Marina¹²³⁴^ORCID,Ramamurthy V.¹⁵⁶⁴^ORCID,Givens Richard S.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. University of Kansas

3. Lawrence

4. USA

5. University of Miami

6. Coral Gables

7. CCMAR - Centre of Marine Sciences

8. University of Algarve

9. Campus de Gambelas

10. Portugal

Abstract

Photolysis of p-hydroxyphenacyloxy arenes releases free phenols in good yields governed by their pK_a. At high pK_a, new byproducts (Bvs. A) reveal a change in reaction mechanism.

Funder

University of Kansas

National Institutes of Health

National Science Foundation

Fundação para a Ciência e a Tecnologia

Publisher

Springer Science and Business Media LLC

Subject

Physical and Theoretical Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/PP/D0PP00067A

Reference58 articles.