Choose your leaving group: selective photodeprotection in a mixture of <i>p</i>HP-caged compounds by VIPER excitation-Reference-Cited by-同舟云学术

Choose your leaving group: selective photodeprotection in a mixture of pHP-caged compounds by VIPER excitation

Published:2023 Issue:10 Volume:14 Page:2624-2630
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

van Wilderen Luuk J. G. W.¹^ORCID,Kern-Michler Daniela¹^ORCID,Neumann Carsten¹,Reinfelds Matiss²^ORCID,von Cosel Jan³,Horz Maximiliane³,Burghardt Irene³^ORCID,Heckel Alexander²^ORCID,Bredenbeck Jens¹^ORCID

Affiliation:

1. Johann Wolfgang Goethe-University, Institute of Biophysics, Max-von-Laue-Str. 1, 60438 Frankfurt am Main, Germany

2. Johann Wolfgang Goethe-University, Institute of Organic Chemistry and Chemical Biology, Max-von-Laue-Str. 7, 60438 Frankfurt am Main, Germany

3. Johann Wolfgang Goethe-University, Institute of Physical and Theoretical Chemistry, Max-von-Laue-Str. 7, 60438 Frankfurt am Main, Germany

Abstract

Combine IR selectivity with UV induced photochemistry. Tune the wavenumber of the IR excitation to the resonance of a specific photocage isotopologue and release the desired leaving group.

Funder

Deutsche Forschungsgemeinschaft

Alexander von Humboldt-Stiftung

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D2SC06259C

Reference57 articles.

1. Wavelength-Selective Uncaging of Two Different Photoresponsive Groups on One Effector Molecule for Light-Controlled Activation and Deactivation

2. A Double Photocage Strategy to Construct Light-Controllable and Spatiotemporally Trackable Cathepsin B Activity-Based Probes

3. Vitamin B12: A Tunable, Long Wavelength, Light-Responsive Platform for Launching Therapeutic Agents

4. Efficient Far-Red/Near-IR Absorbing BODIPY Photocages by Blocking Unproductive Conical Intersections

5. Molecular Engineering of Photoremovable Protecting Groups for Two-Photon Uncaging

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