Target ion and neutral spread in high power impulse magnetron sputtering

Author:

Hajihoseini H.1ORCID,Brenning N.23ORCID,Rudolph M.4ORCID,Raadu M. A.2ORCID,Lundin D.3ORCID,Fischer J.3ORCID,Minea T. M.5ORCID,Gudmundsson J. T.26ORCID

Affiliation:

1. Industrial Focus Group XUV Optics, MESA+ Institute for Nanotechnology, University of Twente, Drienerlolaan 5, 7522 NB Enschede, The Netherlands

2. Space and Plasma Physics, School of Electrical Engineering and Computer Science, KTH Royal Institute of Technology, SE-100 44 Stockholm, Sweden

3. Plasma and Coatings Physics Division, IFM-Materials Physics, Linköping University, SE-581 83 Linköping, Sweden

4. Leibniz Institute of Surface Engineering (IOM), Permoserstraße 15, 04318 Leipzig, Germany

5. Laboratoire de Physique des Gaz et Plasmas—LPGP, UMR 8578 CNRS, Université Paris–Sud, Université Paris–Saclay, 91405 Orsay Cedex, France

6. Science Institute, University of Iceland, Dunhaga 3, IS-107 Reykjavik, Iceland

Abstract

In magnetron sputtering, only a fraction of the sputtered target material leaving the ionization region is directed toward the substrate. This fraction may be different for ions and neutrals of the target material as the neutrals and ions can exhibit a different spread as they travel from the target surface toward the substrate. This difference can be significant in high power impulse magnetron sputtering (HiPIMS) where a substantial fraction of the sputtered material is known to be ionized. Geometrical factors or transport parameters that account for the loss of produced film-forming species to the chamber walls are needed for experimental characterization and modeling of the magnetron sputtering discharge. Here, we experimentally determine transport parameters for ions and neutral atoms in a HiPIMS discharge with a titanium target for various magnet configurations. Transport parameters are determined to a typical substrate, with the same diameter (100 mm) as the cathode target, and located at a distance 70 mm from the target surface. As the magnet configuration and/or the discharge current are changed, the transport parameter for neutral atoms [Formula: see text] remains roughly the same, while transport parameters for ions [Formula: see text] vary greatly. Furthermore, the relative ion-to-neutral transport factors, [Formula: see text], that describe the relative deposited fractions of target material ions and neutrals onto the substrate, are determined to be in the range from 0.4 to 1.1.

Funder

Icelandic Reseach Fund

Free State of Saxony and the European Regional Development Fund

Swedish Government Strategic Research Area in Materials Science on Functional materials at Linkoping University

Publisher

American Vacuum Society

Subject

Surfaces, Coatings and Films,Surfaces and Interfaces,Condensed Matter Physics

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