Medium-size Cyclophanes, 71. Synthesis, Structures and Photo-Induced Cyclisation of 1,2-Diphenyl[2.n]Metacyclophan-1-Enes-Reference-Cited by-同舟云学术

Medium-size Cyclophanes, 71. Synthesis, Structures and Photo-Induced Cyclisation of 1,2-Diphenyl[2.n]Metacyclophan-1-Enes

Published:2006-09 Issue:9 Volume:2006 Page:558-560
ISSN:1747-5198
Container-title:Journal of Chemical Research
language:en
Short-container-title:Journal of Chemical Research

Author:

Yamato Takehiko¹,Saisyo Tatsunori¹,Hironaka Tohru¹,Miyamoto Shinpei¹

Affiliation:

1. Department of Applied Chemistry, Faculty of Science and Engineering, Saga University, Honjo-machi 1, Saga-shi, Saga 840-8502, Japan

Abstract

McMurry cyclisation of 1, n-bis(5-benzoyl-2-methoxyphenyl)alkanes 2 afforded 1,2-diphenyl[2. n]metacyclophan-1-enes 3, which were converted into the corresponding [ n](4,5)phenanthrenophanes 5 by photo-induced cyclisation in the presence of iodine as an oxidant.

Publisher

SAGE Publications

Subject

General Chemistry

Link

http://journals.sagepub.com/doi/pdf/10.3184/030823406778521338

Reference13 articles.

1. Direct Introduction of Bromine onto the Bridged Methylene of 5,13-di-tert-butyl-8,16-dimethyl[2.2]metacyclophane

2. The mechanism of the photoconversion of .alpha.-phenylcinnamic esters into 9,10-dihydrophenanthrenes

3. Molecular geometry and conformational stability of 4,5-dimethyl- and 3,4,5,6-tetramethylphenanthrene: a look at the structural basis of the buttressing effect

4. Aromatic molecules bearing substituents within the cavity of the .pi.-electron cloud. XX. Syntheses of [2.2]metacyclophan-1-enes. Alternate route to trans-15,16-dialkyldihydropyrenes

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3. Medium-Size Cyclophanes. Part 71. Synthesis, Structures and Photo-Induced Cyclization of 1,2-Diphenyl[2.n]metacyclophan-1-enes (IV).;ChemInform;2007-01-09

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