Direct Introduction of Bromine onto the Bridged Methylene of 5,13-di-tert-butyl-8,16-dimethyl[2.2]metacyclophane-Reference-Cited by-同舟云学术

Direct Introduction of Bromine onto the Bridged Methylene of 5,13-di-tert-butyl-8,16-dimethyl[2.2]metacyclophane

Published:2006-08 Issue:8 Volume:2006 Page:493-495
ISSN:1747-5198
Container-title:Journal of Chemical Research
language:en
Short-container-title:Journal of Chemical Research

Author:

Yamato Takehiko¹,Miyamoto Shinpei¹,Okabe Ryo¹,Tazaki Yoshinori¹,Anai Hideyuki¹

Affiliation:

1. Department of Applied Chemistry, Faculty of Science and Engineering, Saga University, Honjo-machi 1, Saga 840-8502, Japan

Abstract

Treatment of 5,13-di- tert-butyl-8,16-dimethyl[2.2]metacyclophane 1 with 1,3-dibromo-5,5-dimethylhydantoin (DBMH) in CH2Cl2 led to the first successful introduction of bromine onto the bridged methylene group.

Publisher

SAGE Publications

Subject

General Chemistry

Link

http://journals.sagepub.com/doi/pdf/10.3184/030823406778256469

Reference12 articles.

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3. 650. The crystal structure of di-m-xylylene

4. Unsymmetrically-substituted [2,2]metacyclophanes via a free-radical substitution reaction

5. Metacyclophanes and related compounds. 12. Reaction of 8,16-dimethyl[2.2]metacyclophane with iodine monochloride

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