Medium-size cyclophanes, 691 Synthesis and ipso-nitration of di-tert-butyl-1,2-dimethyl[2.10]metacyclophan-1-enes-Reference-Cited by-同舟云学术

Medium-size cyclophanes, 691 Synthesis and ipso-nitration of di-tert-butyl-1,2-dimethyl[2.10]metacyclophan-1-enes

Published:2006-06 Issue:6 Volume:2006 Page:393-395
ISSN:1747-5198
Container-title:Journal of Chemical Research
language:en
Short-container-title:Journal of Chemical Research

Author:

Yamato Takehiko¹,Hironaka Tohru¹,Miyamoto Shinpei¹

Affiliation:

1. Department of Applied Chemistry, Faculty of Science and Engineering, Saga University, Honjo-machi 1, Saga 840-8502 Japan

Abstract

Syn-5,21-di- tert-butyl-1,2-dimethyl[2.10]metacyclophan-1-ene syn-4 was prepared by the McMurry reaction of 1,10-bis(3-acetyl-5- tert-butyl-2-methoxyphenyl)decane 3, and nitrated with fuming nitric acid to give the two-fold ipso-nitration product syn-5 in good yield.

Publisher

SAGE Publications

Subject

General Chemistry

Link

http://journals.sagepub.com/doi/pdf/10.3184/030823406777946635

Reference11 articles.

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2. Aromatic molecules bearing substituents within the cavity of the .pi.-electron cloud. XX. Syntheses of [2.2]metacyclophan-1-enes. Alternate route to trans-15,16-dialkyldihydropyrenes

3. Metacyclophanes and related compounds. 4. Halogenations of 8,16-dialkyl-anti-5,13-di-tert-butyl[2.2]metacyclophan-1-enes and 2,7-di-tert-butyl-trans-10b,10c-dialkyl-10b,10c-dihydropyrenes

4. Medium-sized cyclophanes. Part 58. Synthesis and conformational studies of [2.n]metacyclophan-1-enes and [n.1]metacyclophanes

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