Heavy negative ion growth in Titan’s polar winter

Abstract

ABSTRACT A significant but unexpected result of the Cassini mission was the discovery of heavy organic negative ions in Titan’s ionosphere at altitudes between about 950 and 1400 km by the CAPS Electron Spectrometer (ELS). The heaviest ions were observed during the T16 fly-by with masses over 13 000 u/q. This is significantly higher than the maximum masses observed during other fly-bys. We study T16 CAPS-ELS observations and examine the evolution of mass spectra at different altitudes. We also study maximum mass trends using a large data set from all available CAPS-ELS observations of the Cassini mission in order to investigate the conditions necessary to allow negative ions to grow to the highest masses. For the first time, we are able to investigate the relationship between the highest mass particles and seasonal effects. We find that the combination of high latitude and winter conditions, resulting in long-term restricted solar flux, create an environment in which ion growth can reach the highest masses, as observed during T16. Restricting solar flux long term, and hence photodestruction reactions such as photodetachment, appears to be essential for negative ions to grow beyond 10 000 u/q.