Abstract
Abstract. We describe and test a new versatile software tool for
processing eddy covariance and disjunct eddy covariance flux data. We
present an evaluation based on urban non-methane volatile organic compound
(NMVOC) measurements using a proton transfer reaction quadrupole interface
time-of-flight mass spectrometer (PTR-QiTOF-MS) at the Innsbruck Atmospheric
Observatory. The code is based on MATLAB® and can
be easily configured to process high-frequency, low-frequency and disjunct
data. It can be applied to a wide range of analytical setups for NMVOC and other trace gas measurements, and is tailored towards the
application of noisy data, where lag time corrections become challenging.
Several corrections and quality control routines are implemented to obtain
the most reliable results. The software is open source, so it can be
extended and adjusted to specific purposes. We demonstrate the capabilities
of the code based on a large urban dataset collected in Innsbruck, Austria,
where three-dimensional winds and ambient concentrations of NMVOCs and
auxiliary trace gases were sampled with high temporal resolution above an
urban canopy. Concomitant measurements of 12C and 13C isotopic
NMVOC fluxes allow testing algorithms used for determination of flux limits
of detection (LOD) and lag time analysis. We use the high-frequency NMVOC
dataset to generate a set of disjunct data and compare these results with
the true eddy covariance method. The presented analysis allows testing the
theory of disjunct eddy covariance (DEC) in an urban environment. Our
findings confirm that the disjunct eddy covariance method can be a reliable
tool, even in complex urban environments when fast sensors are not
available, but that the increase in random error impedes the ability to
detect small fluxes due to higher flux LODs.
Cited by
11 articles.
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