Author:
Kirner O.,Ruhnke R.,Buchholz-Dietsch J.,Jöckel P.,Brühl C.,Steil B.
Abstract
Abstract. The submodel PSC of the ECHAM5/MESSy Atmospheric Chemistry model (EMAC) has been developed to simulate the main types of polar stratospheric clouds (PSC). The parameterisation of the supercooled ternary solutions (STS, type 1b PSC) in the submodel is based on Carslaw et al. (1995b), the thermodynamic approach to simulate ice particles (type 2 PSC) on Marti and Mauersberger (1993). For the formation of nitric acid trihydrate (NAT) particles (type 1a PSC) two different parameterisations exist. The first is based on an instantaneous thermodynamic approach from Hanson and Mauersberger (1988), the second is new implemented and considers the growth of the NAT particles with the aid of a surface growth factor based on Carslaw et al. (2002). It is possible to choose one of this NAT parameterisation in the submodel. This publication explains the background of the submodel PSC and the use of the submodel with the goal of simulating realistic PSC in EMAC.
Reference67 articles.
1. Abbatt, J. P. D. and Molina, M. J.: The heterogeneous reaction of HOCl + HCl $\\rightarrow $Cl2 + H2O on ice and nitric-acid trihydrate – reaction probabilities and stratospheric implications, Geophys. Res. Lett., 19, 461–464, 1992.
2. Bertram, A. K., Patterson, D. D., and Sloan, J. J.: Mechanisms and temperatures for the freezing of sulfuric acid aerosols measured by FTIR extinction spectroscopy, J. Phys. Chem., 100, 2376–2383, 1996.
3. Beyer, K. D., Seago, S. W., Chang, H. Y., and Molina, M. J.: Composition and freezing of aqueous H2SO4-HNO3 solutions under polar stratospheric conditions, Geophys. Res. Lett., 21, 871–874, 1994.
4. Biermann, U. M., Crowley, J. N., Huthwelker, T., Moortgat, G. K., Crutzen, P. J., and Peter, T.: FTIR studies on lifetime prolongation of stratospheric ice particles due to NAT coating, Geophys. Res. Lett., 25, 3939–3942, 1998.
5. Buchholz, J.: Simulations of physics and chemistry of polar stratospheric clouds with a general circulation model, PhD thesis, Johannes Gutenberg University Mainz, Germany, 2005.
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