Rapid O3 assimilations – Part 1: Background and local contributions to tropospheric O3 changes in China in 2015–2020

Abstract

Abstract. A single ozone (O3) tracer mode was developed in this work to build the capability of the Goddard Earth Observing System model with Chemistry (GEOS-Chem) for rapid O3 simulation. The single O3 tracer simulation demonstrates consistency with the GEOS-Chem full chemistry simulation, with dramatic reductions in computational costs of approximately 91 %–94 %. The single O3 tracer simulation was combined with surface and Ozone Monitoring Instrument (OMI) O3 observations to investigate the changes in tropospheric O3 over eastern China in 2015–2020. The assimilated O3 concentrations demonstrate good agreement with O3 observations because surface O3 concentrations are 43.2, 41.8, and 42.1 ppb and tropospheric O3 columns are 37.1, 37.9, and 38.0 DU in the simulations, assimilations, and observations, respectively. The assimilations indicate rapid rises in surface O3 concentrations by 1.60 (spring), 1.16 (summer), 1.47 (autumn), and 0.80 ppb yr−1 (winter) over eastern China in 2015–2020, and the increasing trends are underestimated by the a priori simulations. More attention is suggested to the rapid increases in the O3 pollution in spring and autumn. We find stronger rises in tropospheric O3 columns over highly polluted areas due to larger local contributions, for example, 0.12 DU yr−1 (North China Plain) in contrast to −0.29 (Sichuan Basin) and −0.25 DU yr−1 (southern China). Furthermore, our analysis demonstrated noticeable contributions of the interannual variability in background O3 to the trends in surface O3 (particularly in the summer) and tropospheric O3 columns over eastern China in 2015–2020. This work highlights the importance of rapid simulations and assimilations to extend and interpret atmospheric O3 observations.