Effect of Hydrogen on the Properties of Amorphous Carbon Nitride Films

Author:

Mikmeková Eliška1,Urbánek Michal1,Fořt Tomáš1,Di Mundo Rosa2,Caha Ondřej3

Affiliation:

1. V.V.I. Academy of Science Czech Republic

2. University of Bari

3. Masaryk University

Abstract

The effect of hydrogen on the properties of amorphous carbon nitride films deposited onto Si substrates by magnetron sputtering device has been studied. The influence of hydrogen to roughness, porous character of films, composition and residual stress was investigated by atomic force microscopy, thermal desorption mass spectroscopy, X-ray photoelectron spectroscopy, scanning low energy electron microscopy and by goniometer equipped with Cu X-ray tube. The adding of hydrogen to nitrogen discharge a causes decrease in the high value of compressive stress (elimination of delamination of the films, increasing of nitrogen content in the bulk). On the other hand hydrogen increases roughness and porosity.

Publisher

Trans Tech Publications, Ltd.

Subject

General Engineering

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3. X. Zhang, K.Z. Chen, R. Ghodssi, A.A. Ayon, S.M. Spearing, Sensors and Actuators 91, 373-380, (2001).

4. N. Hellgren, K. Macak, E. Broitman, M.P. Johansson, L. Hultman, J. -E. Sundgren, J. Appl. Phys. 88 (2000) 524.

5. S. Logotheditis, M. Gioti, P. Patsalas, C. Charitidis, Carbon 9 (375) (2001) 1179.

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