Mechanism of Whisker Growth Suppression by Lead Co-Deposition on Electroplated Tin Film

Author:

Hino Makoto1,Murakami Koji1,Mitooka Yutaka1,Takamizawa Masao2,Naka Toshihide2,Nakai Kiyomichi3

Affiliation:

1. Industrial Technology Research Institute of Okayama Prefectural Government

2. OM Sangyo Co. LTD.

3. Ehime University

Abstract

This study investigated the effect of lead on the whisker growth of a tin film that was the electrodeposited on a phosphor bronze substrate. Subsequent FE-AES observation revealed that the whisker growth on the electrodeposited tin film varied depending on the morphology of the oxide film. The whisker growth was suppressed concomitantly with thinness or fragility of the oxide film formed on the tin deposits. The whisker growth was also suppressed concomitantly with the lead co-deposition in the tin deposits. In the Sn/Sn-Pb multilayer, because the lead between the tin film and the substrate was transferred to the surface, the whisker growth was also suppressed. This whisker growth suppression effect caused by the existence of a lead in the tin deposits was attributed to the oxide film thinning and embrittlement, depending on the lead transfer to the surface at room temperature.

Publisher

Trans Tech Publications, Ltd.

Subject

Mechanical Engineering,Mechanics of Materials,Condensed Matter Physics,General Materials Science

Reference9 articles.

1. NASA Goddard Tin (and other Metal) Whisker WWW Site http: /nepp. nasa. gov/whisker.

2. S.M. Arnold; Plating, 53, 96 (1966).

3. W.J. Boettinger, C.E. Johnson, L.A. Benbersky, K.W. Moon, M.E. Williams and G.R. Stafford: Acta Metar., 53, 5033(2005).

4. W. Zhang and F. Schager:J. Electrochem. Soc., 153, C337-C, 343 (2005).

5. K. Suganuma: UYEMURA TECH. REPORTS, No. 62, 3(2007).

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