Iron-Catalyzed Stereoselective Allylboration of 3,4-Dihydroisoquinolines with Potassium Allyltrifluoroborates-Reference-Cited by-同舟云学术

Iron-Catalyzed Stereoselective Allylboration of 3,4-Dihydroisoquinolines with Potassium Allyltrifluoroborates

Published:2021-04-28 Issue:19 Volume:53 Page:3564-3572
ISSN:0039-7881
Container-title:Synthesis
language:en
Short-container-title:Synthesis

Author:

Fang Yong¹,Hu Xiaoling¹,Luo Yunfei¹^ORCID,Shi Zhuangzhuang¹,Zhao Xu¹,Gopireddy Raveendra Reddy¹²

Affiliation:

1. Anhui Province Key Laboratory of Advanced Catalytic Materials and Reaction Engineering, School of Chemistry and Chemical Engineering, Hefei University of Technology

2. School of Material Science and Engineering, Hefei University of Technology

Abstract

AbstractAn iron-catalyzed allyation of isoquinoline with potassium allyltrifluoroborate is described. The operation of this reaction is very simple and highly practical. The diastereoisomer having two adjacent chiral centers were obtained in single anti-configuration.

Funder

Hefei University of Technology

Fundamental Research Funds for the Central Universities

Ministry of Education of the People’s Republic of China

Publisher

Georg Thieme Verlag KG

Subject

Organic Chemistry,Catalysis

Link

http://www.thieme-connect.de/products/ejournals/pdf/10.1055/a-1493-6420.pdf

Reference7 articles.

1. Catalytic Asymmetric Allylboration of Indoles and Dihydroisoquinolines with Allylboronic Acids: Stereodivergent Synthesis of up to Three Contiguous Stereocenters