Amine adducts of triallylborane as highly reactive allylborating agents for Cu(i)-catalyzed allylation of chiral sulfinylimines

Author:

Alexeev Michael S.12,Strelkova Tatiana V.1,Ilyin Michael M.1,Nelyubina Yulia V.1ORCID,Bespalov Ivan A.34,Medvedev Michael G.13ORCID,Khrustalev Victor N.35ORCID,Kuznetsov Nikolai Yu.12ORCID

Affiliation:

1. A.N. Nesmeyanov Institute of Organoelement compounds, Russian Academy of Sciences, Vavilov st. 28, 119991 Moscow, Russian Federation

2. A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Leninsky Prospect 29, 119991 Moscow, Russian Federation

3. N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Leninsky Prospect 29, 119991 Moscow, Russian Federation

4. Lomonosov Moscow State University, Leninskie Gory 1 (3), Moscow, 119991, Russian Federation

5. Peoples Friendship University of Russia, Miklukho-Maklay st. 6, 117198 Moscow, Russian Federation

Abstract

Convenient, atom-efficient allylation reagents with high selectivity and tunable reactivity, applicable to scale-up synthesis of homoallylamines.

Funder

Russian Science Foundation

Ministry of Education and Science of the Russian Federation

Publisher

Royal Society of Chemistry (RSC)

Reference127 articles.

1. Yu. N.Bubnov , Product Subclass 35: Allylboranes , in Science of Synthesis: Category 1, Organometallics , ed. D. E. Kaufmann , D. S. Matteson , E. Schaumann and M. Regitz , Thieme , Stuttgart , 2005 , vol. 6 , pp. 945–1072

2. D.Hall and H.Lachance , Allylboration of Carbonyl Compounds , Wiley , Hoboken, NJ , 2012

3. D. G.Hall , Boronic Acids , Wiley , Weinheim , 2011

4. S. C.Jonnalagadda , P.Suman , A.Patel , G.Jampana and A.Colfer , Allylboration , in Boron Reagents in Synthesis , ed. A. Coca , ACS Symposium Series, 2016 , ch. 3, vol. 1236 , pp. 67–122

5. Selective reactions using allylic metals

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