d8⋯d10 RhI⋯AuI interactions in Rh 2,6-xylylisocyanide complexes with [Au(CN)2]−: bond analysis and crystal effects-Reference-Cited by-同舟云学术

d8⋯d10 RhI⋯AuI interactions in Rh 2,6-xylylisocyanide complexes with [Au(CN)2]−: bond analysis and crystal effects

Published:2019 Issue:34 Volume:55 Page:5005-5008
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Conejo-Rodríguez Verónica¹²³⁴⁵^ORCID,Peñas-Defrutos Marconi N.¹²³⁴⁵^ORCID,Espinet Pablo¹²³⁴⁵^ORCID

Affiliation:

1. IU CINQUIMA/Química Inorgánica

2. Facultad de Ciencias

3. Universidad de Valladolid

4. 47071-Valladolid

5. Spain

Abstract

The well-known [RhL₄]_n(anion)_n structures, with Rh^I⋯Rh^I d⁸⋯d⁸ interactions, are replaced by others with Rh^I⋯Au^I d⁸⋯d¹⁰ interactions such as [{RhL₄}{Au(CN)₂}] (L = 2,6-xylylisocyanide) or [{RhL₄}{Au(CN)₂}{RhL₄}{Au₂(CN)₃}·4(CHCl₃)]_∞ when the anion is [Au(CN)₂]⁻.

Funder

Consejería de Educación, Junta de Castilla y León

Ministerio de Economía y Competitividad

Ministerio de Educación, Cultura y Deporte

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CC/C9CC01377F

Reference19 articles.

1. Photoinduced Gold(I)-Gold(I) Chemical Bonding in Dicyanoaurate Oligomers

2. Real-Time Observation of Tight Au–Au Bond Formation and Relevant Coherent Motion upon Photoexcitation of [Au(CN)2–] Oligomers

3. Spectroscopic Studies of “Exciplex Tuning” for Dicyanoaurate(I) Ions Doped in Potassium Chloride Crystals

4. Excited-State Interactions for [Au(CN)2-]n and [Ag(CN)2-]n Oligomers in Solution. Formation of Luminescent Gold−Gold Bonded Excimers and Exciplexes

5. Oligomerization of Au(CN)2- and Ag(CN)2- Ions in Solution via Ground-State Aurophilic and Argentophilic Bonding

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