On the nature of recurrent Au⋯π motifs in tris(2,2′-bipyridine)M(ii) (M = Fe, Co and Ni) dicyanoaurate(i) salts: X-ray analysis and theoretical rationalization

Author:

Priola Emanuele1ORCID,Giordana Alessia1ORCID,Mazzeo Paolo P.23ORCID,Mahmoudi Ghodrat4ORCID,Gomila Rosa M.5ORCID,Zubkov Fedor I.6ORCID,Pokazeev Kuzma M.6,Valchuk Karina S.6,Bacchi Alessia23ORCID,Zangrando Ennio7ORCID,Frontera Antonio5ORCID

Affiliation:

1. Department of Chemistry, University of Turin, Via Pietro Giuria 7, 10125 Turin, Italy

2. Dipartimento di Scienze Chimiche, della Vita e della Sostenibilità Ambientale, Università di Parma, Parco Area delle Scienze 17A, 43124 Parma, Italy

3. Biopharmanet-TEC, Università degli studi di Parma, via Parco Area delle Scienze 27/A, 43124 Parma, Italy

4. Department of Chemistry, Faculty of Science, University of Maragheh, P.O. Box 55181-83111, Maragheh, Iran

5. Department of Chemistry, Universitat de les Illes Balears, Crta. de Valldemossa km 7.5, 07122 Palma de Mallorca, Baleares, Spain

6. Faculty of Science, Peoples’ Friendship University of Russia (RUDN University), 6 Miklukho-Maklaya St., Moscow 117198, Russian Federation

7. Department of Chemical and Pharmaceutical Sciences, University of Trieste, Via L. Giorgieri 1, 34127 Trieste, Italy

Abstract

This manuscript provides new physical insight into the nature of recurrent Au⋯π motifs in tris(2,2′-bipyridine)M(ii) (M = Fe, Co and Ni) dicyanoaurate(i) salts by X-ray analysis and theoretical rationalization.

Funder

RUDN University

Ministerio de Ciencia, Innovación y Universidades

Agencia Estatal de Investigación

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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