Mesogenic [Rh(L)4](A) complexes form mesophases with RhI⋯RhI-containing and triphenylene-discotic segregated columns. Effect of RhI⋯RhI interactions and A− = [Au(CN)2]− on hole mobility-Reference-Cited by-同舟云学术

Mesogenic [Rh(L)₄](A) complexes form mesophases with Rh^I⋯Rh^I-containing and triphenylene-discotic segregated columns. Effect of Rh^I⋯Rh^I interactions and A⁻ = [Au(CN)₂]⁻ on hole mobility

Published:2023 Issue:4 Volume:11 Page:1435-1447
ISSN:2050-7526
Container-title:Journal of Materials Chemistry C
language:en
Short-container-title:J. Mater. Chem. C

Author:

Conejo-Rodríguez Verónica¹^ORCID,Donnio Bertrand²^ORCID,Heinrich Benoît²^ORCID,Termine Roberto³^ORCID,Golemme Attilio³^ORCID,Espinet Pablo¹^ORCID

Affiliation:

1. IU CINQUIMA/Química Inorgánica, Facultad de Ciencias, Universidad de Valladolid, E-47071 Valladolid, Spain

2. Institut de Physique et Chimie des Matériaux de Strasbourg (IPCMS), UMR 7504 (CNRS-Université de Strasbourg), F-67034 Strasbourg Cedex 2, France

3. LASCAMM CR-INSTM, CNR-Nanotec, Dipartimento di Fisica, 87036 Rende, Italy

Abstract

[Rh(CNAr)4](A) complexes of polyalkoxytriphenylene-arylisocyanide ligands form deeply coloured mesophases with segregated triphenylene/metal-complex columns at −9–169 °C with hole mobility 2 to 4 orders of magnitude higher than organic triphenylenes.

Funder

Ministerio de Asuntos Económicos y Transformación Digital, Gobierno de España

Université de Strasbourg

Ministerio de Ciencia e Innovación

Centre National de la Recherche Scientifique

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/TC/D2TC02272A

Reference85 articles.