Soft X-ray signatures of cationic manganese–oxo systems, including a high-spin manganese(<scp>v</scp>) complex-Reference-Cited by-同舟云学术

Soft X-ray signatures of cationic manganese–oxo systems, including a high-spin manganese(v) complex

Published:2022 Issue:6 Volume:24 Page:3598-3610
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Delcey Mickaël G.¹^ORCID,Lindblad Rebecka²³⁴^ORCID,Timm Martin³⁵^ORCID,Bülow Christine³⁶,Zamudio-Bayer Vicente³^ORCID,von Issendorff Bernd⁶^ORCID,Lau J. Tobias³⁶^ORCID,Lundberg Marcus¹^ORCID

Affiliation:

1. Department of Chemistry - Ångström Laboratory, Uppsala University, SE-75120 Uppsala, Sweden

2. Department of Physics, Lund University, Box 118, SE-22100 Lund, Sweden

3. Abteilung für Hochempfindliche Röntgenspektroskopie, Helmholtz-Zentrum Berlin für Materialien und Energie, Albert-Einstein-Str. 15, 12489 Berlin, Germany

4. Inorganic Chemistry, Department of Chemistry - Ångström Laboratory, Uppsala University, SE-75121 Uppsala, Sweden

5. Institut für Optik und Atomare Physik, Technische Universität Berlin, Hardenbergstr. 36, 10623 Berlin, Germany

6. Physikalisches Institut, Albert-Ludwigs-Universität Freiburg, Hermann-Herder-Str. 3, 79104, Freiburg, Germany

Abstract

Limitations in synthesis of high-valent metal–oxo complexes are circumvented by trapping a series of ionic Mn–oxo complexes. One of them is a rare high-spin Mn(v)–oxo, which can serve as a template to identify similar intermediates in catalysis.

Funder

Knut och Alice Wallenbergs Stiftelse

Stiftelsen Olle Engkvist Byggmästare

Bundesministerium für Bildung und Forschung

Vetenskapsrådet

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CP/D1CP03667J

Reference126 articles.