Direct spectroscopic evidence for the high-spin state of dioxidomanganese(<scp>v</scp>)-Reference-Cited by-同舟云学术

Direct spectroscopic evidence for the high-spin state of dioxidomanganese(v)

Published:2024 Issue: Volume: Page:
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Ablyasova Olesya S.¹²^ORCID,Zamudio-Bayer Vicente¹^ORCID,Flach Max¹²^ORCID,da Silva Santos Mayara¹²^ORCID,Lau J. Tobias¹²^ORCID,Hirsch Konstantin¹^ORCID

Affiliation:

1. Abteilung für Hochempfindliche Röntgenspektroskopie, Helmholtz-Zentrum Berlin für Materialien und Energie, Albert-Einstein-Str. 15, Berlin 12489, Germany

2. Physikalisches Institut, Albert-Ludwigs-Universität Freiburg, Hermann-Herder-Str. 3, Freiburg 79104, Germany

Abstract

The spin state of metal centers in catalytic reactions can be rate limiting when high-valent metals such as manganese are involved. Here, we demonstrate dioxidomanganese(v) to be only the second manganese(v) compound to exhibit a high spin state.

Funder

Deutsche Forschungsgemeinschaft

Bundesministerium für Bildung und Forschung

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CP/D3CP05468C

Reference66 articles.

1. Iron and manganese oxo complexes, oxo wall and beyond

2. Transition metal-mediated O–O bond formation and activation in chemistry and biology

3. Singlet versus Triplet Reactivity in an Mn(V)–Oxo Species: Testing Theoretical Predictions Against Experimental Evidence

4. The reactivity of the active metal oxo and hydroxo intermediates and their implications in oxidations

5. Spin State as a Marker for the Structural Evolution of Nature’s Water-Splitting Catalyst