Direct synthesis of 8-acylated quinoline N-oxidesviapalladium-catalyzed selective C–H activation and C(sp2)–C(sp2) cleavage
Author:
Affiliation:
1. College of Chemistry and Pharmaceutical Sciences
2. Qingdao Agricultural University
3. Qingdao 266109
4. P. R. China
5. School of Chemistry and Chemical Engineering
6. Hunan University of Science and Technology
7. Xiangtan 411201
8. China
Abstract
An efficient method for the synthesis of 8-acylated quinoline N-oxides from the reaction of quinoline N-oxides with α-diketonesviaC–C bond cleavage was developed. A variety of quinoline N-oxides and α-diketones with different groups was well tolerated in this system.
Funder
National Natural Science Foundation of China
China Postdoctoral Science Foundation
Qingdao Agricultural University
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,General Chemistry,Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2019/NJ/C8NJ05374J
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