Photochemical organocatalytic enantioselective radical γ-functionalization of α-branched enals-Reference-Cited by-同舟云学术

Photochemical organocatalytic enantioselective radical γ-functionalization of α-branched enals

Published:2022 Issue:41 Volume:58 Page:6072-6075
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Balletti Matteo¹²^ORCID,Marcantonio Enrico¹^ORCID,Melchiorre Paolo¹³^ORCID

Affiliation:

1. ICIQ – Institute of Chemical Research of Catalonia – the Barcelona Institute of Science and Technology, Av. Països Catalans 16, 43007 Tarragona, Spain

2. Department of Analytical Chemistry and Organic Chemistry, University Rovira i Virgili (URV), 43007 Tarragona, Spain

3. ICREA – Catalan Institution for Research and Advanced Studies, Pg. Lluís Companys 23, 08010 Barcelona, Spain

Abstract

Reported herein is a rare example of asymmetric catalytic functionalisation of enals at the remote γ-position, proceeding via a radical path.

Funder

Agencia Estatal de Investigación

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CC/D2CC01638A

Reference42 articles.

1. Walking Metals for Remote Functionalization

2. Remote functionalization through alkene isomerization

3. Recent trends in Pd-catalyzed remote functionalization of carbonyl compounds

4. Extended Enolates: Versatile Intermediates for Asymmetric C‐H Functionalization via Noncovalent Catalysis

5. Palladium-Catalyzed Enantioselective Heck Alkenylation of Acyclic Alkenols Using a Redox-Relay Strategy

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