Electrophilic Fluorination of Silyl Dienol Ethers: a General and Selective Access to γ‐Fluoro Enals-Reference-Cited by-同舟云学术

Electrophilic Fluorination of Silyl Dienol Ethers: a General and Selective Access to γ‐Fluoro Enals

Published:2023-12-28 Issue: Volume: Page:
ISSN:0947-6539
Container-title:Chemistry – A European Journal
language:en
Short-container-title:Chemistry A European J

Author:

Li Yang¹^ORCID,Briand Marina¹,Miqueu Karinne²^ORCID,Anselmi Elsa¹³^ORCID,Magnier Emmanuel¹^ORCID,Dagousset Guillaume¹^ORCID

Affiliation:

1. Université Paris-Saclay UVSQ, CNRS, UMR 8180 Institut Lavoisier de Versailles 45 avenue des Etats-Unis 78000 Versailles France

2. CNRS/Université de Pau et des Pays de l'Adour E2S-UPPA Institut des Sciences Analytiques et de Physico-Chimie pour l'Environnement et les Matériaux (IPREM UMR 5254) Hélioparc 2 Avenue du Président Angot 64053 Pau Cedex 09 France

3. Université de Tours Faculté des Sciences et Techniques 37200 Tours France

Abstract

AbstractWe describe the direct synthesis of γ‐fluoro enals from the corresponding silyl dienol ethers. This simple process operates under mild conditions and is compatible with a wide range of functionalities. The high γ regioselectivity of this protocol was rationalized by means of theoretical calculations.

Publisher

Wiley

Subject

General Chemistry,Catalysis,Organic Chemistry

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2. Glycal-Derived δ-Hydroxy α,β-Unsaturated Aldehydes (Perlin Aldehydes): Versatile Building Blocks in Organic Synthesis

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