Aluminium salalens vs. salans: “Initiator Design” for the isoselective polymerisation of rac-lactide-Reference-Cited by-同舟云学术

Aluminium salalens vs. salans: “Initiator Design” for the isoselective polymerisation of rac-lactide

Published:2016 Issue:68 Volume:52 Page:10431-10434
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

McKeown Paul¹²³⁴⁵,Davidson Matthew G.⁵²³⁴,Kociok-Köhn Gabriele⁵²³⁴,Jones Matthew D.⁵²³⁴

Affiliation:

1. Doctoral Training Centre in Sustainable Chemical Technologies

2. University of Bath

3. Bath BA2 7AY

4. UK

5. Department of Chemistry

Abstract

Minor modification of ligand structure leads to interesting structural isomerism on complexation and a profound improvement of initiator activity.

Funder

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CC/C6CC05795K

Reference37 articles.

1. Ring-Opening Polymerization of rac-Lactide with Aluminum Chiral Anilido-Oxazolinate Complexes

2. Aluminium salalen complexes based on 1,2-diaminocyclohexane and their exploitation for the polymerisation of rac-lactide

3. Remarkable Stereocontrol in the Polymerization of Racemic Lactide Using Aluminum Initiators Supported by Tetradentate Aminophenoxide Ligands

4. Stereocontrolled Polymerization of Racemic Lactide with Chiral Initiator: Combining Stereoelection and Chiral Ligand-Exchange Mechanism

5. Stereoselective Ring-Opening Polymerization of Racemic Lactide Using Aluminum-Achiral Ligand Complexes: Exploration of a Chain-End Control Mechanism

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