Aluminium complexes of phenoxy-azo ligands in the catalysis of rac-lactide polymerisation

Author:

Sumrit Pattarawut12,Kamavichanurat Sirawan12ORCID,Joopor Wasan12ORCID,Wattanathana Worawat3ORCID,Nakornkhet Chutikan12ORCID,Hormnirun Pimpa12ORCID

Affiliation:

1. Laboratory of Catalysts and Advanced Polymer Materials, Department of Chemistry and Centre of Excellence for Innovation in Chemistry, Faculty of Science, Kasetsart University, Bangkok 10900, Thailand

2. Centre for Advanced Studies in Nanotechnology for Chemical, Food and Agricultural Industries, Kasetsart University, Bangkok 10900, Thailand

3. Department of Materials Engineering, Faculty of Engineering, Kasetsart University, Bangkok 10900, Thailand

Abstract

Two series of phenoxy-azo aluminium complexes were successfully synthesised and characterised. All aluminium complexes are active initiators for the ROP of rac-lactide, and the polymerisations proceeded in a controlled manner and were living.

Funder

Kasetsart University Research and Development Institute

Graduate School, Kasetsart University

Ministry of Education

Kasetsart University

Publisher

Royal Society of Chemistry (RSC)

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