Stereo-electronic contributions in yttrium-mediated stereoselective ring-opening polymerization of functional<i>racemic</i>β-lactones: ROP of 4-alkoxymethylene-β-propiolactones with bulky exocyclic chains-Reference-Cited by-同舟云学术

Stereo-electronic contributions in yttrium-mediated stereoselective ring-opening polymerization of functionalracemicβ-lactones: ROP of 4-alkoxymethylene-β-propiolactones with bulky exocyclic chains

Published:2023 Issue:6 Volume:14 Page:720-727
ISSN:1759-9954
Container-title:Polymer Chemistry
language:en
Short-container-title:Polym. Chem.

Author:

Shakaroun Rama M.¹,Dhaini Ali¹,Ligny Romain¹,Alaaeddine Ali²,Guillaume Sophie M.¹^ORCID,Carpentier Jean-François¹^ORCID

Affiliation:

1. Univ. Rennes, CNRS, Institut des Sciences Chimiques de Rennes, UMR 6226, F-35042 Rennes, France

2. Univ. Libanaise, Campus Universitaire Rafic Hariri Hadath, Faculté des Sciences, Laboratoire de Chimie Médicinale et des Produits Naturels, Beirut, Lebanon

Abstract

ROP of bulky functional β-lactones mediated by an achiral diamino-bis(phenolate) yttrium catalyst affords syndio-enriched polyhydroxyalkanoates.

Funder

Région Bretagne

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Link

http://pubs.rsc.org/en/content/articlepdf/2023/PY/D2PY01573K

Reference43 articles.

1. Controlled Ring-Opening Polymerization of Lactide and Glycolide