Ring-opening (co)polymerization of chiral seven-membered lactones mediated by achiral yttrium catalysts: insights into the catalyst stereocontrol by mass spectrometry-Reference-Cited by-同舟云学术

Ring-opening (co)polymerization of chiral seven-membered lactones mediated by achiral yttrium catalysts: insights into the catalyst stereocontrol by mass spectrometry

Published:2024 Issue:19 Volume:15 Page:1975-1991
ISSN:1759-9954
Container-title:Polymer Chemistry
language:en
Short-container-title:Polym. Chem.

Author:

Dhaini Ali¹,Ollivier Jérôme¹,Le Yondre Nicolas²,Alaaeddine Ali³,Guillaume Sophie M.¹^ORCID,Carpentier Jean-François¹^ORCID

Affiliation:

1. Univ. Rennes, CNRS, Institut des Sciences Chimiques de Rennes, UMR 6226, F-35042 Rennes, France

2. Univ. Rennes, Centre Régional de Mesures Physiques de l'Ouest, UAR 2025 ScanMAT, F-35042 Rennes, France

3. Univ. Libanaise, Campus Universitaire Rafic Hariri Hadath, Faculté des Sciences, Laboratoire de Chimie Médicinale et des Produits Naturels, Beirut, Lebanon

Abstract

The ROCOP of equimolar mixtures of (R)-CLnBu/(S)-CLMe enabled the assessment of the ROP stereocontrol ability of yttrium catalysts through the degree of alternation via detailed mass spectrometric analyses.

Funder

Université de Rennes 1

Université Libanaise

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/PY/D4PY00330F

Reference52 articles.

1. Beyond Stereoselectivity, Switchable Catalysis: Some of the Last Frontier Challenges in Ring-Opening Polymerization of Cyclic Esters

2. Toward Infinitely Recyclable Plastics Derived from Renewable Cyclic Esters

3. Stereochemical enhancement of polymer properties

4. Controlling polymer stereochemistry in ring-opening polymerization: a decade of advances shaping the future of biodegradable polyesters

5. Ring-Opening Polymerization for the Goal of Chemically Recyclable Polymers