Distortion-driven spin switching in electron-doped metal porphyrins-Reference-Cited by-同舟云学术

Distortion-driven spin switching in electron-doped metal porphyrins

Published:2022 Issue:26 Volume:10 Page:9748-9757
ISSN:2050-7526
Container-title:Journal of Materials Chemistry C
language:en
Short-container-title:J. Mater. Chem. C

Author:

Cojocariu Iulia¹²^ORCID,Carlotto Silvia³⁴^ORCID,Jugovac Matteo¹²^ORCID,Floreano Luca⁵^ORCID,Casarin Maurizio³,Feyer Vitaliy¹⁶^ORCID,Schneider Claus Michael¹⁶

Affiliation:

1. Peter Grunberg Institute (PGI-6), Forschungszentrum Julich GmbH, Leo-Brandt-Strase, Julich, 52428, Germany

2. Elettra-Sincrotrone, S.C.p.A, S.S. 14 - km 163.5 in AREA Science Park, Trieste, 34149, Italy

3. Dipartimento di Scienze Chimiche, Universita degli Studi di Padova, via F. Marzolo 1, Padova, 35131, Italy

4. Institute of Condensed Matter Chemistry and Technologies for Energy (ICMATE), National Research Council (CNR), c/o Department of Chemistry, University of Padova, via F. Marzolo 1, Padova, 35131, Italy

5. CNR-IOM, Lab. TASC, S.S. 14 - km 163.5 in AREA Science Park, Trieste, 34149, Italy

6. Fakultat f. Physik and Center for Nanointegration Duisburg-Essen (CENIDE), Universitat Duisburg-Essen, Lotharstrase 1, Duisburg, 47048, Germany

Abstract

Different conformers can be stabilized for flexible porphyrins upon electron doping. The metastable flat conformer relaxes to the energetically favored distorted form, inducing spin switching in the chelated nickel ion.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/TC/D2TC01253G

Reference59 articles.

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