Extended π-conjugation: a key to magnetic anisotropy preservation in highly reactive porphyrins-Reference-Cited by-同舟云学术

Extended π-conjugation: a key to magnetic anisotropy preservation in highly reactive porphyrins

Published:2023 Issue:44 Volume:11 Page:15521-15530
ISSN:2050-7526
Container-title:Journal of Materials Chemistry C
language:en
Short-container-title:J. Mater. Chem. C

Author:

Cojocariu Iulia¹²³^ORCID,Carlotto Silvia⁴⁵^ORCID,Baranowski Daniel²^ORCID,Jugovac Matteo²³^ORCID,Dreiser Jan⁶^ORCID,Schio Luca⁷^ORCID,Floreano Luca⁷^ORCID,Casarin Maurizio⁴,Feyer Vitaliy²⁸^ORCID,Schneider Claus M.²⁸⁹

Affiliation:

1. Dipartimento di Fisica, Università degli Studi di Trieste, via A. Valerio 2, 34127 Trieste, Italy

2. Peter Grünberg Institute (PGI-6), Forschungszentrum Jülich GmbH, Leo-Brandt-Straße, 52428 Jülich, Germany

3. Elettra-Sincrotrone, S.C.p.A, S.S 14 – km 163.5, 34149 Trieste, Italy

4. Dipartimento di Scienze Chimiche, Università degli Studi di Padova, via F. Marzolo 1, 35131 Padova, Italy

5. Institute of Condensed Matter Chemistry and Technologies for Energy (ICMATE), National Research Council (CNR), c/o Department of Chemistry, University of Padova, via F. Marzolo 1, 35131 Padova, Italy

6. Swiss Light Source, Paul Scherrer Institut, CH-5232 Villigen PSI, Switzerland

7. CNR-IOM, Lab. TASC, s.s. 14 km 163,5, 34149 Trieste, Italy

8. Fakultät f. Physik and Center for Nanointegration Duisburg-Essen (CENIDE), Universität Duisburg-Essen, D-47048 Duisburg, Germany

9. Department of Physics and Astronomy, UC Davis, Davis, CA 95616, USA

Abstract

The findings herein reported highlight the role played by planarization in quenching the reactivity and preserving the magnetic anisotropy. The effect is associated with the weakening of the ligand field, which accompanies the π-conjugation increase.

Funder

Università degli Studi di Padova

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/TC/D3TC02726K

Reference55 articles.

1. Quantum computing in molecular magnets

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5. Supramolecular control of the magnetic anisotropy in two-dimensional high-spin Fe arrays at a metal interface

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