Stereocontrolled construction of six vicinal stereogenic centers on a hexahydroxanthone framework through a formal [2+1+3] annulation-Reference-Cited by-同舟云学术

Stereocontrolled construction of six vicinal stereogenic centers on a hexahydroxanthone framework through a formal [2+1+3] annulation

Published:2019 Issue:93 Volume:55 Page:14003-14006
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Chang Shun-Qin¹²³⁴,Zou Xiong¹²³⁴,Gong Yi¹²³⁴⁵,He Xue-Wen¹²³⁴,Liu Xiong-Li¹²³⁴^ORCID,Zhou Ying⁵⁶³⁴

Affiliation:

1. Guizhou Engineering Center for Innovative Traditional Chinese Medicine and Ethnic Medicine

2. Guizhou University

3. Guiyang

4. P. R. China

5. College of Pharmaceutical Sciences

6. Guizhou University of Traditional Chinese Medicine

Abstract

The first example of a bifunctional donor–donor 3C synthon formed in situ from an activated methine with nitromethane through a [2+1] Michael addition, further directing a one-pot organocascade Michael/Henry cycloaddition was developed.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CC/C9CC08101A

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