Reactions of co-ordinated ligands. Part 53. Synthesis of dimolybdenum and ditungsten µ-σ,η2-(4e)-vinylidene and -allenylidene complexes; crystal structures of [N(PPh3)2][Mo2{µ-σ:η2-(3e)-C2Ph}(CO)4(η5-C9H7)2], [Mo2{µ-σ:η2-(4e)-CC(Ph)(CH2)4OMe}(CO)4(η-C5H5)2] and [Mo2{µ-σ:η2-(4e)-CCCMe2}(CO)4(η-C5H5)2]
Author:
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/1991/DT/DT9910003171
Reference27 articles.
1. Reactions of co-ordinated ligands. Part 52. Formation and reactivity of molybdenum vinylidene anions; crystal structures of [Mol(η4-CH2CHCHCHCH2But){P(OMe)3}(η-C5H5)] and [Mo(η3-CButCHCHCMe2CO){P(OMe)3}2(η-C5H5)]
2. F. A. Cotton and R. A.Walton, Multiple Bonds between Metal Atoms, Wiley, New York, 1982, p. 245.
3. Cp2M2(CO)4 - quadruply bridging, doubly bridging, semibridging, or nonbridging?
4. Evidence for a facile switch in the bonding mode of µ-vinylidene ligands from σ, η2to σ,σ; synthesis and structure of a dinuclear µ-σ,η2-allenylidene complex
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