Reactions of co-ordinated ligands. Part 52. Formation and reactivity of molybdenum vinylidene anions; crystal structures of [Mol(η4-CH2CHCHCHCH2But){P(OMe)3}(η-C5H5)] and [Mo(η3-CButCHCHCMe2CO){P(OMe)3}2(η-C5H5)]-Reference-Cited by-同舟云学术

Reactions of co-ordinated ligands. Part 52. Formation and reactivity of molybdenum vinylidene anions; crystal structures of [Mol(η4-CH2CHCHCHCH2But){P(OMe)3}(η-C5H5)] and [Mo(η3-CButCHCHCMe2CO){P(OMe)3}2(η-C5H5)]

Published:1991 Issue:11 Volume: Page:3021-3030
ISSN:0300-9246
Container-title:J. Chem. Soc., Dalton Trans.
language:en
Short-container-title:J. Chem. Soc., Dalton Trans.

Author:

Beevor Robert G.,Freeman Mark J.,Green Michael,Morton Carolyn E.,Orpen A. Guy

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/1991/DT/DT9910003021

Reference16 articles.

1. Reactions of co-ordinated ligands. Part 51. The reactions of σ,η3(5e)-butadienylruthenium complexes [Ru{C(Ph)-η3-C(Ph)C(Ph)CR(Ph)}(η-C5H5)](R = H or CHO) with P(OMe)3, PhCCPh, H+and aryldiazonium cations; crystal structure of [Ru{C(O)C(Ph)C(Ph)-η2-(Z)C(Ph)CH(Ph)}{P(OMe)3}(η-C5H5)]

2. Synthesis and reactions of molybdenum vinyl complexes. Evidence for formation of carbyne complexes

3. Reactions of co-ordinated ligands. Part 39. The synthesis of carbyne complexes from alkyne molybdenum and tungsten cations; formation and crystal structures of [Mo(CCH2But){P(OMe)3}2(η-C5H5)] and [Mo{C(SiMe3)CH2}{P(OMe)3}2(η5-C9H7)]

4. Evidence of the base-promoted conversion of alkyl-substituted molybdneum and tungsten alkylidyne complexes into anionic vinylalkylidene species

5. The role of metallacyclopropenes in the formation of alkylidyne complexes; evidence for a 1,2-trimethylsilyl shift and the X-ray crystal structure of [MoC(SiMe3)CH2{P(OMe)3}2(η5-C9H7)]

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