Reactions of co-ordinated ligands. Part 51. The reactions of σ,η3(5e)-butadienylruthenium complexes [Ru{C(Ph)-η3-C(Ph)C(Ph)CR(Ph)}(η-C5H5)](R = H or CHO) with P(OMe)3, PhCCPh, H+and aryldiazonium cations; crystal structure of [Ru{C(O)C(Ph)C(Ph)-η2-(Z)C(Ph)CH(Ph)}{P(OMe)3}(η-C5H5)]
Author:
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/1991/DT/DT9910001589
Reference13 articles.
1. Reactions of co-ordinated ligands. Part 50. The synthesis of functionalised η3-allyl complexes of molybdenum and their conversion into η4-s-trans-1,3-dienes
2. Reaction of cationic cyclobutadineruthenium complexes with hydride anion donors; evidence for the formation of η4(5e) butadienyl species and fragmentation of the cyclobutadiene ring: crystal structure of [RuC(Ph)–η3-{C(Ph)·CH(Ph)·CH(Ph)}-(η-C5H5)] and [Ru2(µ-CO){µ-(Z)-C(Ph)CH(Ph)}(CO)2(η4-C4Ph4)(η-C5H5)]
3. Reactions of coordinated ligands. Part 47. Synthesis, structure, and reactivity of [.eta.4(5e)-butadienyl]ruthenium complexes: crystal structures of CpRu:C(Ph)-.eta.3-[C(Ph)C(Ph)CH(Ph)], CpRuC(Ph):C(Ph)-.eta.2-[C(Ph):CH(Ph)]P(OMe)3, and CpRu2[.mu.-(Z)-C(Ph):CH(Ph)](CO)2(.eta.4-C4Ph4)
4. The reactions of σ,η3-butadienylruthenium complexes with donor ligands and protons: structures of [RuC(Ph)C(Ph)-η2-{(Z)-C(Ph)CH(Ph)}{P(OMe)3}(η-C5H5)] and [RuC(O)C(Ph)C(Ph)-η2-{(Z)-C(Ph)CH(Ph)}{P(OMe)3}(η-C5H5)]
5. Normal and anomalous ring opening of 1-3-.eta.-pentaarylcyclobutenylpalladium complexes
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