Metallacumulenylidene Complexes in the Cycloheptatrienyl Molybdenum Series [Mo{(C)n═CR2}L2(η-C7H7)]+ (n = 0−2; L2 = P-Donor Ligand). X-ray Crystal Structures of [Mo{C═C(H)Ph}{P(OMe)3}2(η-C7H7)][BF4] and [Mo(C═C═CPh2)(dppe)(η-C7H7)][PF6] and DFT Investigation of Cumulenylidene Ligand Orientations-Reference-Cited by-同舟云学术

Metallacumulenylidene Complexes in the Cycloheptatrienyl Molybdenum Series [Mo{(C)n═CR2}L2(η-C7H7)]+ (n = 0−2; L2 = P-Donor Ligand). X-ray Crystal Structures of [Mo{C═C(H)Ph}{P(OMe)3}2(η-C7H7)][BF4] and [Mo(C═C═CPh2)(dppe)(η-C7H7)][PF6] and DFT Investigation of Cumulenylidene Ligand Orientations

Published:2008-02-06 Issue:5 Volume:27 Page:857-871
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Grime Richard W.¹,Helliwell Madeleine¹,Hussain Zaffar I.¹,Lancashire Hannah N.¹,Mason Christopher R.¹,McDouall Joseph J. W.¹,Mydlowski Christopher M.¹,Whiteley Mark W.¹

Affiliation:

1. School of Chemistry, University of Manchester, Manchester M13 9PL, U.K.

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om700920t

Reference63 articles.

1. Transition Metal Complexes Containing Allenylidene, Cumulenylidene, and Related Ligands

2. Metal complexes containing cumulenylidene ligands, {LmM}C(C)nCRR′(n≥2)

3. Transition Metal Chemistry of 1,3-Diynes, Poly-ynes, and Related Compounds

4. Metal Alkynyl σ Complexes: Synthesis and Materials

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