A structural parameter to link molecular geometry to macroscopic orientation in discotic liquid crystals: study of metalloporphyrin tapes-Reference-Cited by-同舟云学术

A structural parameter to link molecular geometry to macroscopic orientation in discotic liquid crystals: study of metalloporphyrin tapes

Published:2021 Issue:10 Volume:57 Page:1206-1209
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Kobayashi Yoshiyuki¹²³⁴⁵,Muranaka Atsuya⁶⁷⁸⁹⁵^ORCID,Kato Kenichi¹⁰¹¹⁵,Saeki Akinori¹²¹³¹⁴¹⁵⁵^ORCID,Tanaka Takayuki¹⁶¹⁷¹⁸¹⁹⁵^ORCID,Uchiyama Masanobu⁶⁷⁸⁹⁵^ORCID,Osuka Atsuhiro¹⁶¹⁷¹⁸¹⁹⁵,Aida Takuzo¹²³⁴⁵^ORCID,Sakurai Tsuneaki¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry and Biotechnology

2. School of Engineering

3. The University of Tokyo

4. Tokyo

5. Japan

6. Cluster of Pioneering Research (CPR)

7. Advanced Elements Chemistry Laboratory

8. RIKEN

9. Saitama

10. RIKEN SPring-8 Center

11. Hyogo

12. Department of Applied Chemistry

13. Graduate School of Engineering

14. Osaka University

15. Osaka

16. Department of Chemistry

17. Graduate School of Science

18. Kyoto University

19. Kyoto 606-8502

Abstract

A meso-alkyl triply-linked dimeric porphyrin tape forms a columnar liquid crystal mesophase, in which the macroscopic orientation of columns drastically changes depending on the choice of central metal ions.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CC/D0CC07241A

Reference38 articles.

1. Discotic liquid crystals of transition metal complexes, Part 30: spontaneous uniform homeotropic alignment of octakis(dialkoxyphenoxy)phthalocyaninatocopper(ii) complexes

2. Control of the Homeotropic Order of Discotic Hexa-peri-hexabenzocoronenes

3. Microfocus X-ray Diffraction Study of the Columnar Phase of Porphyrin-Based Mesogens

4. Alignment behaviour of symmetrical and asymmetrical triphenylenes possessing fluoroalkylated side chains on modified substrates

5. Homeotropic and Planar Alignment of Discotic Liquid Crystals: The Role of the Columnar Mesophase

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