Columnar liquid crystals based on antiaromatic expanded porphyrins

Author:

Nguyen Duong D.1,Labella Jorge2ORCID,Laforga-Martín Juan2,Folcia César L.3ORCID,Ortega Josu3ORCID,Torres Tomás245ORCID,Sierra Teresa6ORCID,Sessler Jonathan L.1ORCID

Affiliation:

1. Department of Chemistry, The University of Texas at Austin, 105 E 24th Street, A5300, Austin, TX, 78712, USA

2. Department of Organic Chemistry, Universidad Autónoma de Madrid, Campus de Cantoblanco, C/Francisco Tomás y Valiente 7, Madrid 28049, Spain

3. Department of Physics, Faculty of Science and Technology, UPV/EHU, Bilbao, Spain

4. Institute for Advanced Research in Chemical Sciences (IAdChem), Universidad Autónoma de Madrid, Madrid 28049, Spain

5. IMDEA-Nanociencia, Campus de Cantoblanco, Madrid 28049, Spain

6. Instituto de Nanociencia y Materiales de Aragón (INMA), Departamento de Química Orgánica, Facultad de Ciencias, CSIC-Universidad de Zaragoza, Zaragoza 50009, Spain

Abstract

Antiaromatic expanded porphyrins designed to self-assemble into columnar liquid crystalline (LC) structures are synthesized and characterized by multiple techniques. The substituents were found to play a crucial role in modulating the LC behaviour.

Funder

Welch Foundation

Ministerio de Ciencia e Innovación

Comunidad de Madrid

European Commission

Ministerio de Asuntos Económicos y Transformación Digital, Gobierno de España

Alexander von Humboldt-Stiftung

Ministerio de Educación, Cultura y Deporte

Gobierno de Aragón

Eusko Jaurlaritza

Universidad de Zaragoza

Publisher

Royal Society of Chemistry (RSC)

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