The coordination behaviour and reactivity of partially silicon based crown ethers towards beryllium chloride-Reference-Cited by-同舟云学术

The coordination behaviour and reactivity of partially silicon based crown ethers towards beryllium chloride

Published:2018 Issue:46 Volume:47 Page:16393-16397
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Buchner Magnus R.¹²³⁴⁵^ORCID,Müller Matthias¹²³⁴⁵,Dankert Fabian⁶⁴⁵⁷^ORCID,Reuter Kirsten⁶⁴⁵⁷,von Hänisch Carsten⁶⁴⁵⁷^ORCID

Affiliation:

1. Anorganische Chemie

2. Nachwuchsgruppe Berylliumchemie

3. Fachbereich Chemie

4. Philipps-Universität Marburg

5. 35032 Marburg

6. Fachbereich Chemie and Wissenschaftliches Zentrum für Materialwissenschaften (WZMW)

7. Germany

Abstract

The reaction of partially silicon based crown ethers with BeCl₂ yields eight-membered Be–O-heterocycles, which are annulated by two six-membered Be–O-cycles.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/DT/C8DT03963A

Reference30 articles.

1. Hydrogen Bonding Studies. V. The Relative Basicities of Ethers, Alkoxysilanes and Siloxanes and the Nature of the Silicon-Oxygen Bond1,2

2. Silicon Analogues of Crown Ethers and Cryptands: A New Chapter in Host–Guest Chemistry?

3. 117. The reaction of methyldisiloxanes and 1 : 1-dimethyldisilthiane with boron and hydrogen halides

4. Siloxane basicity toward strong acid in nonpolar solution

5. Unsupported metal silyl ether coordination

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