Hydrolysis and oxidation products of phosphine adducts to beryllium chloride

Abstract

Abstract The synthesis of bis(diphenylphosphino)ethane (dppe) and PMe3 mono-adducts [(dppe)BeCl2]n and [(PMe3)BeCl2]2 is described and their spectroscopic properties discussed. Hydrolysis of these two compounds and of the bis(diphenylphosphino)propane (dppp) adduct to BeCl2 gave [dppeH2][BeCl4], [Me3PH]n[Be4Cl9]n and [dpppH2][Be2Cl6], which have been isolated and structurally characterized by single crystal X-ray diffraction. The reactions of [(PMe3)BeCl2]2 with p-cresole gave [Me3PH]2[Be2Cl4(OC7H7)2]. This phenoxide together with [(Me3PO)2Be2Cl4], the oxidation product of [(PMe3)BeCl2]2, have also been structurally characterized.