A Personal Account on Inorganic Reaction Mechanisms

Author:

Polaczek Justyna1,Kieca Konrad12,Oszajca Maria1,Impert Olga3,Katafias Anna3,Chatterjee Debabrata34,Ćoćić Dušan5,Puchta Ralph678,Stochel Grażyna1,Hubbard Colin D.9,van Eldik Rudi63

Affiliation:

1. Faculty of Chemistry Jagiellonian University Gronostajowa 2 30-387 Kraków Poland

2. Jagiellonian University Doctoral School of Exact and Natural Sciences, Kraków 30-348 Krakow Poland

3. Faculty of Chemistry Nicolaus Copernicus University in Torun Gagarina 7 87-100 Torun Poland

4. Vice-Chancellor's Research Group Zoology Department University of Burdwan Burdwan 713104 India

5. University of Kragujevac Faculty of Science Department of Chemistry Radoja Domanovića 12, P. O. Box 60 34000 Kragujevac Serbia

6. Department of Chemistry and Pharmacy University of Erlangen-Nuremberg Egerlandstrasse 1 91058 Erlangen Germany

7. Central Institute for Scientific Computing (CISC) University of Erlangen-Nuremberg Martensstr. 5a 91058 Erlangen Germany

8. Computer Chemistry Center Department of Chemistry and Pharmacy University of Erlangen-Nuremberg Nägelsbachstr. 25 91052 Erlangen Germany

9. Department of Chemistry University of New Hampshire Durham 03824 USA

Abstract

AbstractThe presented Review is focused on the latest research in the field of inorganic chemistry performed by the van Eldik group and his collaborators. The first part of the manuscript concentrates on the interaction of nitric oxide and its derivatives with biologically important compounds. We summarized mechanistic information on the interaction between model porphyrin systems (microperoxidase) and NO as well as the recent studies on the formation of nitrosylcobalamin (CblNO). The following sections cover the characterization of the Ru(II)/Ru(III) mixed‐valence ion‐pair complexes, including Ru(II)/Ru(III)(edta) complexes. The last part concerns the latest mechanistic information on the DFT techniques applications. Each section presents the most important results with the mechanistic interpretations.

Funder

Narodowe Centrum Nauki

Publisher

Wiley

Subject

Materials Chemistry,General Chemical Engineering,Biochemistry,General Chemistry

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