Offsets between hyperconjugations, p→d donations and Pauli repulsions impact the bonding of E–O–E systems. Case study on elements of Group 14-Reference-Cited by-同舟云学术

Offsets between hyperconjugations, p→d donations and Pauli repulsions impact the bonding of E–O–E systems. Case study on elements of Group 14

Published:2022 Issue:21 Volume:24 Page:13217-13228
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Moraru Ionut-Tudor¹^ORCID,Teleanu Florin¹^ORCID,Silaghi-Dumitrescu Luminita¹^ORCID,Nemes Gabriela¹^ORCID

Affiliation:

1. Faculty of Chemistry and Chemical Engineering, Department of Chemistry, Babeş-Bolyai University, 1 M. Kogalniceanu Street, RO-400084 Cluj-Napoca, Romania

Abstract

The different structures of organic and inorganic ethers can be explained by a new bonding image based on offsets between secondary attractive interactions and vicinal Pauli repulsions, describing a wide range of E–O–E systems (E = C, Si, Ge, Sn).

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CP/D2CP00869F

Reference95 articles.

1. THE ATOM AND THE MOLECULE.

2. The Physical Mechanism of the Chemical Bond

3. The Lewis electron-pair bonding model: the physical background, one century later

4. R. J.Gillespie and P. L.-A.Popelier , Chemical Bonding and Molecular Geometry , Oxford University Press , London , 2001

5. Chemical Bonding in Higher Main Group Elements

Cited by 2 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Coordination Ability of Phosphavinyl(oxo and thioxo)phosphoranes (P═C–P═X; X = O, S) toward Transition Metals;Organometallics;2024-09-06

2. In silico modelling of chelate stabilized tetrylene derivatives;RSC Advances;2024