Cyaphide–alkynyl complexes: metal–ligand conjugation and the influence of remote substituents

Author:

Furfari Samantha K.1234ORCID,Leech Matthew C.1234ORCID,Trathen Nicola1234,Levis Madeleine C.1234ORCID,Crossley Ian R.1234ORCID

Affiliation:

1. Department of Chemistry

2. University of Sussex

3. Brighton

4. UK

Abstract

A series of cyaphide–alkynyl complexes exhibits significant cooperativity between the electron accepting “–CP” ligand and remote alkynyl substituents, indicative of long-range communication.

Funder

Royal Society

Leverhulme Trust

Engineering and Physical Sciences Research Council

University of Sussex

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference55 articles.

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2. R. Appel , in Multiple Bonds and Low Coordination in Phosphorus Chemistry , ed. M. Regitz and O. J. Scherer , Thieme , Stutgart , 1990

3. Phosphaalkynes and phosphaalkenes

4. Phospha-alkenes and Phospha-alkynes, Genesis and Properties of the(p-p)π-Multiple Bond

5. K. B. Dillon , F.Mathey and J. F.Nixon , Phosphorus: The Carbon Copy , Wiley , Chichester , 1998

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