Putting cyaphide in its place: determining the donor/acceptor properties of the κ<i>C</i>-cyaphido ligand-Reference-Cited by-同舟云学术

Putting cyaphide in its place: determining the donor/acceptor properties of the κC-cyaphido ligand

Published:2023 Issue:17 Volume:14 Page:4627-4632
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Yang Eric S.¹^ORCID,Combey Emma¹,Goicoechea Jose M.²^ORCID

Affiliation:

1. Department of Chemistry, University of Oxford, Chemistry Research Laboratory, 12 Mansfield Rd., Oxford, OX1 3TA, UK

2. Department of Chemistry, Indiana University, 800 East Kirkwood Ave., Bloomington, Indiana, 47405, USA

Abstract

The σ-donor and π-acceptor properties of the cyaphide ion (CP–) are compared to other well-established strong-field ligands allowing us to assess the relative position of this unique ion in the spectrochemical series.

Funder

University of Oxford

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D3SC01126G

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