Unusual coordination mode for 1,3-diphosphete ligands towards a Cr–Cr quintuple bond complex-Reference-Cited by-同舟云学术

Unusual coordination mode for 1,3-diphosphete ligands towards a Cr–Cr quintuple bond complex

Published:2023 Issue:55 Volume:59 Page:8588-8591
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Elsayed Moussa M.¹,Rummel E.-M.¹,Balázs G.¹,Riesinger C.¹,Noor A.²³^ORCID,Kempe R.²,Scheer M.¹^ORCID

Affiliation:

1. Department of Inorganic Chemistry, University of Regensburg, D93040, Regensburg, Germany

2. Department of Inorganic Chemistry, University of Bayreuth, D95440, Bayreuth, Germany

3. Department of Basic Sciences, Preparatory Year Deanship, King Faisal University, 31982 Al-Hassa, Saudi Arabia

Abstract

The reaction of the phosphaalkynes RCP (R =tBu, Me) with a Cr–Cr quintuple bond complex leads to 1,3-diphosphete ligands with an unprecedented coordination mode. When AdCP is used instead, a side-on coordination of the phosphaalkyne is realised.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CC/D3CC01358H

Reference55 articles.

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2. Oligomerization of phosphaalkynes mediated by bulky N-heterocyclic carbenes: avenues to novel phosphorus frameworks

3. Di‐ tert ‐butyldiphosphatetrahedrane: Catalytic Synthesis of the Elusive Phosphaalkyne Dimer

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