Direct functionalization of white phosphorus with anionic dicarbenes and mesoionic carbenes: facile access to 1,2,3-triphosphol-2-ides-Reference-Cited by-同舟云学术

Direct functionalization of white phosphorus with anionic dicarbenes and mesoionic carbenes: facile access to 1,2,3-triphosphol-2-ides

Published:2019 Issue:48 Volume:10 Page:11078-11085
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Rottschäfer Dennis¹²³⁴⁵^ORCID,Blomeyer Sebastian¹²³⁴⁵^ORCID,Neumann Beate¹²³⁴⁵,Stammler Hans-Georg¹²³⁴⁵,Ghadwal Rajendra S.¹²³⁴⁵^ORCID

Affiliation:

1. Molecular Inorganic Chemistry and Catalysis

2. Inorganic and Structural Chemistry

3. Center for Molecular Materials

4. Faculty of Chemistry

5. Universität Bielefeld

Abstract

A series of unique C₂P₃-ring compounds [(ADC^Ar)P₃] (4) are readily accessible in an almost quantitative yield by the direct functionalization of white phosphorus (P₄) with appropriate anionic dicarbenes [Li(ADC^Ar)].

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/SC/C9SC04441H

Reference70 articles.

1. D. E. C. Corbridge , Phosphorus: Chemistry, Biochemistry and Technology , CRC Press , 6th edn, 2016

2. New Routes for the Functionalization of P4

3. Early-Transition-Metal-Mediated Activation and Transformation of White Phosphorus

4. P4 Activation by Late-Transition Metal Complexes

5. Coordination chemistry and functionalization of white phosphorus via transition metal complexes

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