P4 Activation by Late-Transition Metal Complexes
Author:
Affiliation:
1. Istituto di Chimica dei Composti Organometallici, Consiglio Nazionale delle Ricerche (ICCOM-CNR), Via Madonna del Piano 10, 50019 Sesto Fiorentino (Firenze), Italy
Publisher
American Chemical Society (ACS)
Subject
General Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/cr900349u
Reference299 articles.
1. Rhodium complexes with the molecular unit P4 as a ligand
2. Curiously, the first pnictido complexes ever reported were the cobalt complexes [Co(CO)3(cyclo-As3)], [Co2(CO)6(µ,η2:2-As2)], and [{Co2(CO)5(PPh3)}(µ,η2:2-As3)], which contained naked arsenic units as ligands. See:
3. Organometallic pnicogen complexes. III. Preparation and structural characterization of the triarsenic-cobalt atom cluster system As3Co(CO)3. The first known X3-transition metal analog of group VA tetrahedral X4 molecules
4. Organometallic pnicogen complexes. IV. Synthesis, structure, and bonding of new organometallic arsenic-metal atom clusters containing a metal-bridged multiply bonded As2 ligand: Co2(CO)6As2 and Co2[(CO)5PPh3]As2
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