Unexpected metal ion-assisted transformations leading to unexplored bridging ligands in NiII coordination chemistry: the case of PO3F2− group-Reference-Cited by-同舟云学术

Unexpected metal ion-assisted transformations leading to unexplored bridging ligands in NiII coordination chemistry: the case of PO3F2− group

Published:2014 Issue:39 Volume:43 Page:14520-14524
ISSN:1477-9226
Container-title:Dalton Trans.
language:en
Short-container-title:Dalton Trans.

Author:

Dermitzaki Despina¹²³,Raptopoulou Catherine P.⁴⁵⁶⁷⁸,Psycharis Vassilis⁴⁵⁶⁷⁸,Escuer Albert⁹¹⁰¹¹,Perlepes Spyros P.¹²³,Stamatatos Theocharis C.¹¹²¹³

Affiliation:

1. Department of Chemistry

2. University of Patras

3. 265 04 Patras, Greece

4. Institute of Advanced Materials

5. Physicochemical Processes

6. Nanotechnology and Microsystems

7. NCSR “Demokritos”

8. 153 10 Agia Paraskevi Attikis, Greece

9. Departament de Quimica Inorganica

10. Universitat de Barcelona

11. 08028 Barcelona, Spain

12. Brock University

13. L2S 3A1 St. Catharines, Canada

Abstract

The bridging potency of the O-rich PO₃F²⁻ group in Ni^II/oximate chemistry has been studied leading to interesting coordination compounds and revealing an unprecedented PO₃F²⁻ to P₂O₅F₂²⁻in situ transformation.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/DT/C4DT02204A

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