Induced fac–mer rearrangements in {M(CO)3}+ complexes (M = Re, 99(m)Tc) by a PNP ligand-Reference-Cited by-同舟云学术

Induced fac–mer rearrangements in {M(CO)₃}⁺ complexes (M = Re, ^99(m)Tc) by a PNP ligand

Published:2024 Issue:4 Volume:53 Page:1434-1438
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Besmer Manuel Luca¹^ORCID,Schwitter Flurina¹,Battistin Federica¹^ORCID,Braband Henrik¹^ORCID,Fox Thomas¹,Spingler Bernhard¹^ORCID,Alberto Roger¹^ORCID

Affiliation:

1. Department of Chemistry, University of Zurich, Winterthurerstrasse 190, CH-8057 Zurich, Switzerland

Abstract

The fac–mer isomerisation in [MX3(CO)3]2− (M = Re, 99Tc) is induced by a PNP pincer-type ligand in the presence of a halide scavenger. The adaptation to the aqueous and saline chemistry of 99mTc yields mer-[99mTc(PNP)(CO)3]+.

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D3DT03992G

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