Migrating hydrogen in 2,4,6-triaminopyrimidinium(1+) x hydrogen trioxofluorophosphate(−) x monohydrate/2,4,6-triaminopyrimidinium(2+)1–x trioxofluorophosphate(2–)1–x monohydrate (0.0 < x < 0.73) with changing temperature

Abstract

The data of the title structure of 2,4,6-triaminopyrimidinium(1+) x hydrogen trioxofluorophosphate(1−) x monohydrate/2,4,6-triaminopyrimidinium(2+)1−x trioxofluorophosphate(2−)1−x monohydrate (0.0 < x < 0.73), with the sum formula C4H11FN5O4P, were collected in 10 K intervals between 290 and 150 K, as well as at 100 K. The most interesting feature is the presence of a moderate though still strong O—H...N/O...H—N hydrogen bond. Its bridging H atom was found to be disordered over two positions in the temperature interval 290–220 K, with the larger occupation towards the O atom. The occupation in the latter position decreased with decreasing temperature, though not monotonously. At 210 K and below, the difference electron-density maps showed just one maximum which was closer to the N atom. Though difference scanning calorimetry (DSC) revealed no anomaly in the interval 303–93 K, the dependence of the length of the unit-cell axes b and c on temperature showed a kink in the slope at about 190 K. The N...O distance of the mentioned hydrogen bond or the occupational parameter of the electron density of the disordered H atom indicate less pronounced anomalies for the temperatures 270 and 230 K. The cation and the anion, as well as the water molecules, form layers which are parallel to (10\overline{1}) and which are interconnected by O—H...N (in the interval 290–220 K), N—H...O and O—H...O hydrogen bonds of moderate strength. The layers are arranged into centrosymmetric double layers in which the F atoms are directed outwards. The layers are interconnected by water–acid O—H...O hydrogen bonds, weak N—H...F interactions and π-electron ring...π-electron ring interactions. The dependence of P—F bond lengths on bonding properties of the trioxofluorophosphate or hydrogen trioxofluorophosphate anions is discussed. It has been recognized that a carbon-bonded F atom avoids participation in a hydrogen-bond pattern; however, this property seems to be also common to fluorine bonded to P, As and S, especially if an oxygen ligand is also present in a molecule. The deposited material contains an overview of the determined structures with trioxofluorophosphate or hydrogen trioxofluorophosphate anions.