Aerobic oxidation of primary amines to amides catalyzed by an annulated mesoionic carbene (MIC) stabilized Ru complex-Reference-Cited by-同舟云学术

Aerobic oxidation of primary amines to amides catalyzed by an annulated mesoionic carbene (MIC) stabilized Ru complex

Published:2021 Issue:21 Volume:11 Page:7018-7028
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Yadav Suman¹,Reshi Noor U Din¹,Pal Saikat¹,Bera Jitendra K.¹^ORCID

Affiliation:

1. Department of Chemistry and Centre for Environmental Sciences and Engineering, Indian Institute of Technology Kanpur, Kanpur 208016, India

Abstract

A Ru complex, stabilized by an annulated mesoionic carbene ligand, catalyzes the aerobic oxidation of a host of primary amines to amides in high yields and excellent selectivity. Kinetics, Hammett and DFT studies provide mechanistic insight.

Funder

Science and Engineering Research Board

University Grants Commission

Indian Institute of Technology Kanpur

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CY/D1CY01541A

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